Thermodynamic properties of N-alkane mixtures energy of mixing. Energy of mixing
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 62, 3044-3045
- https://doi.org/10.1039/tf9666203044
Abstract
Van Laar and Lorenz established a relation which allows one to calculate the heat of “mixing with zero volume change”. We have extended their result to the mixing of normal alkanes, which is accompanied by a contraction, by interpreting the factor a of the van der Waals equation and by supposing that a pure normal paraffin may be considered for this purpose as a mixture of CH3 and CH2 molecules.Keywords
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