KINETIC STUDY ON THE FORMATION OF A BINUCLEAR COMPLEX BETWEEN COPPER(II) AND CYCLODEXTRIN
- 5 September 1976
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 5 (9) , 963-966
- https://doi.org/10.1246/cl.1976.963
Abstract
The formation of a 2:1 complex between copper(II) and α- or β-cyclodextrin was examined in an alkaline solution by means of a stopped-flow spectrophotometer. The reaction involves a first-order rate process corresponding to the cross-linking of a cyclodextrin ring by a Cu(OH−)2Cu or Cu(OH−)(O2−)Cu ion bridge.Keywords
This publication has 4 references indexed in Scilit:
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- Ligand solvation and the macrocyclic effect. Nickel(II)-tetramine complexesInorganic Chemistry, 1974
- Complexes of Copper(II) with CyclodextrinsBulletin of the Chemical Society of Japan, 1972
- Macrocyclic effect on the stability of copper(II) tetramine complexesJournal of the American Chemical Society, 1969