Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis
- 1 August 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (34) , 11882-11883
- https://doi.org/10.1021/ja042736s
Abstract
Ruthenium alkylidene complexes containing one aryloxide “pseudohalide” ligand catalyze ring-closing metathesis of diene and ene-yne substrates with exceptionally high efficiency. Chromatographic removal of Ru residues is unexpectedly facile, offering a convenient means of isolating pure organic products in high yields.Keywords
This publication has 36 references indexed in Scilit:
- Nitro-Substituted Hoveyda−Grubbs Ruthenium Carbenes: Enhancement of Catalyst Activity through Electronic ActivationJournal of the American Chemical Society, 2004
- Handbook of MetathesisPublished by Wiley ,2003
- A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of AcrylonitrileAngewandte Chemie International Edition in English, 2002
- A Highly Efficient Ruthenium Catalyst for Metathesis ReactionsAngewandte Chemie International Edition in English, 2002
- A New Highly Efficient Ruthenium Metathesis Catalyst This work was supported by the Fonds der Chemischen Industrie.Angewandte Chemie International Edition in English, 2002
- A Highly Active and Air-Stable Ruthenium Complex for Olefin Metathesis This work was supported by the Fonds der Chemischen Industrie.Angewandte Chemie International Edition in English, 2002
- A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis CatalystsOrganometallics, 2001
- Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene LigandsOrganic Letters, 1999
- Olefin Metathesis-Active Ruthenium Complexes Bearing a Nucleophilic Carbene LigandJournal of the American Chemical Society, 1999
- A Novel Class of Ruthenium Catalysts for Olefin MetathesisAngewandte Chemie International Edition in English, 1998