Nickel catalysed asymmetric coupling reaction between allyl phenyl ethers and Grignard reagents
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 112-114
- https://doi.org/10.1039/c39830000112
Abstract
The asymmetric allylation of Grignard reagents by allyl phenyl ethers in the presence of [(–)-(S,S)-2,3-bis (diphenylphosphino) butane](II) chloride gives rise to optically active olefins, with fair to high optical yields; asymmetric induction in the synthesis of 3-ethylcyclohex-1-ene exceeds 97%.Keywords
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