1,3-Stereoinduction in Radical Additions to Glyoxylate Imines
- 1 July 1998
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1998 (7) , 780-782
- https://doi.org/10.1055/s-1998-1763
Abstract
Addition of alkyl radicals to the acyclic glyoxylate imine 1 proceeded with a 70 : 30 stereoinduction, even at -78 °C. Addition to the cyclic imine 4b resulted in complete stereocontrol at -40 °C.Keywords
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