Ion pair complexes form the reduction of metal(II)-dibenzotetramethyltetra-aza[14]annulene complexes
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 281-283
- https://doi.org/10.1039/c39870000281
Abstract
Ion pair complexes, [M(tmtaa)Na(thf)3](M = Fe, Co, or Ni; tmtaa = dibenzotetramethyltetra-aza[14]annulene dianion; thf = tetrahydrofuran), in which both metal ions are associated with the macrocyclic ligand have been obtained form single-electron reduction of the parent metal(II) compounds with sodium metal; the crystal structure of one of the complexes is reported.Keywords
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