Lifting of vibrational degeneracies in a crystal field
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 69, 262-269
- https://doi.org/10.1039/f29736900262
Abstract
This paper gives an account of the calculation of the magnitude of the splitting of the bending modes of linear triatomic ions, HF– 2 and N– 3 due (a) to the electrostatic field of the crystal containing the ions and (b) to the coupling of oscillators in a primitive unit cell. The observed splittings are used to calculate the magnitude of the charge moving during the vibration.Keywords
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