Reaction of [60]Fullerene with Terbium(IV) Fluoride
- 1 May 1998
- journal article
- research article
- Published by Taylor & Francis in Fullerene Science and Technology
- Vol. 6 (3) , 469-479
- https://doi.org/10.1080/10641229809350215
Abstract
A reaction between [60]fullerene and terbium(IV) fluoride is shown to be a new example of the thermally induced disruption of the fullerene skeleton. “Hyperfluorination” occurs at the elevated temperature (350° C) thereby producing species C60 Fx (x > 60). The fluorination products were characterized by mass spectrometry and IR spectroscopy methods.Keywords
This publication has 11 references indexed in Scilit:
- Perfluorofullerenes: Characterization and structural aspectsJournal of Physics and Chemistry of Solids, 1996
- Preparation of C60F36 and C70F36/38/40Chemical Communications, 1996
- Hyperfluorination of [60]fullerene by krypton difluorideJournal of the Chemical Society, Perkin Transactions 2, 1995
- Preparation and Characterization of Fluorinated FullerenesFullerene Science and Technology, 1993
- Hyperfluorination of buckminsterfullerene: cracking the sphereJournal of the American Chemical Society, 1993
- Characterization and stability of highly fluorinated fullerenesThe Journal of Physical Chemistry, 1992
- Exo-fluorinated C60F60 has Ih symmetryChemical Physics Letters, 1992
- Theoretical study of buckminsterfullerene derivatives C60Xn (X=H, F; n=2, 36, 60)Chemical Physics Letters, 1992
- Fluorinated fullerenesJournal of the American Chemical Society, 1991
- Fluorination of buckminsterfullereneJournal of the Chemical Society, Chemical Communications, 1991