The synthesis and X-ray structure analysis of Os6(CO)17(NC5H5)2: a cluster compound with an unusual mode of metal–CO bonding
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1089-1090
- https://doi.org/10.1039/c39840001089
Abstract
Reaction of the neutral hexaosmium cluster Os6(CO)18 with excess of pyridine (py) gives the pentanuclear dianion [Os5(CO)15]2– together with small amounts of a neutral hexanuclear cluster Os6(CO)17(py)2(1); X-ray analysis shows that (1) exhibits an unusual type of metal–carbonyl linkage.Keywords
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