The reaction between nickel carbonyl and thiophosgene (CSCI2) and the supposed polymeric carbon monosulphide of dewar)
- 1 January 1937
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 56 (4) , 359-364
- https://doi.org/10.1002/recl.19370560408
Abstract
The amorphous, brownish black substance obtained by Dewar and Jones from nickel carbonyl and thiophosgene, has not the composition (CS)x but contains organically combined chlorine. The reaction has been carried out in various solvents; the amorphous reaction products have been completely analysed and it appears that the solid adsorbs the solvent, which cannot be completely removed. The C: S ratio in these products therefore varies from 1: 0.8 to 1: 0.9.The reaction was also carried out in the vapour phase. The amorphous product so obtained also contained organically combined chlorine while the C:S ratio was 1: 1.03 in this case.Thus the product produced from nickel carbonyl and thiophosgene is not a polymeric form of carbon monosulphide.Keywords
This publication has 9 references indexed in Scilit:
- The sulfides of carbonJournal of Chemical Education, 1931
- On the behaviour of amorphous carbon and sulphur, compared with the behaviour of diamond and of graphite and on the carbon sulphide of ciusaRecueil des Travaux Chimiques des Pays-Bas, 1930
- Company newsJournal of the Society of Chemical Industry, 1926
- On the behaviour of sulphur and amorphous carbon at high temperaturesRecueil des Travaux Chimiques des Pays-Bas, 1924
- Sur la Façon Dont se Comportent le Carbone Amorphe et le Soufre Lorsqu'on Les Chauffe. Les Sulfures du Carbone: (2e communication)Recueil des Travaux Chimiques des Pays-Bas, 1922
- PERCHLORO-METHYL-MERCAPTAN.1Journal of the American Chemical Society, 1921
- Le soufre des houilles. Recherches sur le soufre inorganique et organique de la houille et ses transformations pendant la fabrication du coke. Expériences sur la détermination quantitative de la pyrite de la houilleRecueil des Travaux Chimiques des Pays-Bas et de la Belgique, 1919
- On the gaseous condensable compound, explosive at low temperatures, produced from carbon disulphide vapour by the action of the silent electric discharge.—IIProceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1911
- The change of carbon disulphide into a gaseous product condensable and explosive near the temperature of liquid airProceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1910