Formation of allyl sulphide synthons by [1,2] and [1,3] shifts of the phenylthio group
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 820-821
- https://doi.org/10.1039/c39750000820
Abstract
Allyl phenyl sulphides, made from 2-hydroxy-alkyl phenyl sulphides by acid-catalysed rearrangement of the phenylthio group, may be isomerised by the [1,3] allylic shift of the same group, and converted into 4-hydroxy carbonyl compounds or allyl alcohols.Keywords
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