Electrical conductivity of microemulsions : a case of stirred percolation
- 1 January 1979
- journal article
- Published by EDP Sciences in Journal de Physique Lettres
- Vol. 40 (14) , 331-333
- https://doi.org/10.1051/jphyslet:019790040014033100
Abstract
The electrical conductivity G of water in oil microemulsions may be described by percolation models [1] : below a critical water concentration Øc, G seems to diverge as (Øc - Ø)- S', while for Ø > Øc G increases as (Ø - Ø c)-T'. This physical situation may be called stirred percolation, referring to the Brownian motion of the medium. The exponents S' and T' are a priori different from the corresponding S and T in the classical situation of frozen percolation. A simple model of stirred percolation accounts fairly well for the measured value of S' = 1.2 ± 0.1 while the accepted value for S is 0.7. The exponent T' (1.4 to 1.6 in our experimental case) is less significant of the difference between stirred and frozen percolation : the values for S' should be about 1.8 and the value accepted for S should be about 1.6Keywords
This publication has 3 references indexed in Scilit:
- A structural description of liquid particle dispersions: Ultracentrifugation and small angle neutron scattering studies of microemulsionsThe Journal of Chemical Physics, 1978
- Study of structure and electrical conductivity in microemulsions : Evidence for percolation mechanism and phase inversionJournal de Physique Lettres, 1978
- Percolation and ConductionReviews of Modern Physics, 1973