Terminal substitution and cage incorporation of an η-cyclopentadienyl ring into borane cage structures; crystal structures of [Mo (η-C₅H₅)(η⁵:η¹-C₅H₄)B₄H₇] and [Mo(η-C₅H₅)(η³:η²-C₃H₃)C₂B₉H₉]

1 January 1989

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 18,p. 1397-1399
https://doi.org/10.1039/c39890001397

Abstract

The synthesis and crystal structure of the molybdaborane [Mo(η-C₅H₅)(η⁵:η¹-C ₅H₄)B₄H₇](1) and of the molybdacarbaborane [Mo(η-C₅H₅)(η³:η²-C₃H₃)C₂B₉H₉](2) formed via cyclopentadienyl ring activation are reported.

Keywords

CRYSTAL STRUCTURE

This publication has 0 references indexed in Scilit:

Terminal substitution and cage incorporation of an η-cyclopentadienyl ring into borane cage structures; crystal structures of [Mo (η-C5H5)(η5:η1-C5H4)B4H7] and [Mo(η-C5H5)(η3:η2-C3H3)C2B9H9]

Abstract

Keywords

Terminal substitution and cage incorporation of an η-cyclopentadienyl ring into borane cage structures; crystal structures of [Mo (η-C₅H₅)(η⁵:η¹-C₅H₄)B₄H₇] and [Mo(η-C₅H₅)(η³:η²-C₃H₃)C₂B₉H₉]