On the Reactivity of Phosphate Monoester Dianions in Aqueous Solution: Brønsted Linear Free-Energy Relationships Do Not Have an Unique Mechanistic Interpretation
- 21 October 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 120 (44) , 11524-11525
- https://doi.org/10.1021/ja982698a
Abstract
No abstract availableThis publication has 14 references indexed in Scilit:
- Langevin Dipoles Model for ab Initio Calculations of Chemical Processes in Solution: Parametrization and Application to Hydration Free Energies of Neutral and Ionic Solutes and Conformational Analysis in Aqueous SolutionThe Journal of Physical Chemistry B, 1997
- A Fundamental Assumption about OH- Attack in Phosphate Ester Hydrolysis Is Not Fully JustifiedJournal of the American Chemical Society, 1997
- Mapping the transition state for ATP hydrolysis: implications for enzymatic catalysisChemistry & Biology, 1995
- Linear Free Energy Relationships in Enzymes. Theoretical Analysis of the Reaction of Tyrosyl-tRNA SynthetaseJournal of the American Chemical Society, 1994
- Do pentacoordinate oxyphosphorane intermediates always exist?Journal of the American Chemical Society, 1993
- Existence of a marginally stable intermediate during the base-catalyzed methanolysis of methylene phosphate and ab initio studies of the monohydration of the pentacoordinated oxyphosphorane intermediateJournal of the American Chemical Society, 1991
- Nonexistence of dianionic pentacovalent intermediates in an ab initio study of the base-catalyzed hydrolysis of ethylene phosphateJournal of the American Chemical Society, 1990
- The reactivity of phosphate esters: reactions of monoesters with nucleophiles. Nucleophilicity independent of basicity in a bimolecular substitution reactionJournal of the Chemical Society B: Physical Organic, 1968
- The Reactivity of Nucleophilic Reagents toward the p-Nitrophenyl Phosphate Dianion1Journal of the American Chemical Society, 1965
- Mechanisms of Nucleophilic Substitution in Phosphate EstersChemical Reviews, 1964