Excitation spectrum associated with a generalized antisymmetrized geminal power ground state
- 1 February 1982
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 25 (2) , 650-657
- https://doi.org/10.1103/physreva.25.650
Abstract
Self-consistent polarization-propagator approximations (i.e., those based on a proper vacuum) are compared to conventional time-dependent Hartree-Fock — random-phaseapproximation ones, with special attention to the fulfillment of the -sum rule. The effect on the properties of the consistent propagator, based on a general-antisymmetrizedgeminal-power vacuum, when degeneracies occurring in the first-order reduced-density matrix of this vacuum are examined. The foregoing analysis shows that low-lying electronic states can be expected to become degenerate with the vacuum in conjunction with superphenomena in extended systems and oscillator-strength anomalies in finite ones.
Keywords
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