C3 cyclopolymerization. I. Is the cyclopolymerization of 1,3‐bis(p‐vinylphenyl)‐propane by means of radical or anionic initiators possible?

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Abstract
Polymerization of 1,3‐bis(p‐vinylphenyl) propane (St‐C3‐St) was investigated by using radical and anionic initiators. Radical polymerization yielded linear polymer with pendant styryl groups in pertinent conditions without gelation. Anionic polymerization with n‐butyllithium and sodium naphthalene produced insoluble polymers that, according to infrared (IR) spectroscopy, had no cyclized units. On the other hand, phenylmagnesium bromide gave soluble polymer in HMPA‐benzene mixed solvent. Zero‐valent nickel catalyst also gave soluble polymer. The soluble polymers could be analyzed by several spectroscopies, and it was confirmed that those obtained by anionic and coordination polymerization had no [3.3]paracyclophane units in the main chain. From these results it was concluded that cationic propagation could be assumed if the polymer Of St‐C3‐St contained [3.3]paracyclophane units in the main chain.