Stereospecific introduction of a C-17 side chain in a 14β-hydroxy-steroid; X-ray crystal structures of two epimeric 17-ethynyl-17-hydroxy-14β-hydroxy-steroids
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 363-364
- https://doi.org/10.1039/c39810000363
Abstract
Stereospecific introduction of a C-17 side chain in a 14β-hydroxy-steroid was carried out using acetylenic lithium or Grignard reagents; unequivocal proof of the structures of the two products was derived from single-crystal X-ray analyses.Keywords
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