Heats of Mixing for Binary Mixtures. The Energy of Hydrogen Bonding between Alcohol and Ketone Molecules
- 1 December 1964
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 37 (12) , 1776-1780
- https://doi.org/10.1246/bcsj.37.1776
Abstract
A microcalorimeter of the twin type has been constructed, one which is operated semiautomatically. Using this apparatus, the heats of mixing for alcohol-ketone, alcohol-hexane, and ketone-hexane solutions have been measured. From these heats of mixing, the hydrogen bond energy of the O–H…O= type has been estimated to be about 4kcal. by means of the thermochemical cycle.Keywords
This publication has 4 references indexed in Scilit:
- Thermodynamical Studies on Binary Systems Consisting of Polar and Non-polar Liquids. I. Construction of a Semi-automatic Microcalorimeter Suitable for the Rapid Measurement of Heats of Mixing of Binary SolutionsBulletin of the Chemical Society of Japan, 1961
- Thermodynamic and spectroscopic properties of associated solutions. Part 3Transactions of the Faraday Society, 1953
- Cooperative Orientation Effects in SolutionsThe Journal of Chemical Physics, 1952
- Internal Equilibria and Partial Vapor Pressures of Mixtures of Primary Normal Alcohols with Normal Paraffin HydrocarbonsThe Journal of Chemical Physics, 1934