Formation of substituted cyclohexadienyl tricarbonylmanganese complexes by nucleophilic addition reactions of functionally substituted (η-arene)tricarbonylmanganese cations
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 16-17,p. 1683-1686
- https://doi.org/10.1039/dt9750001683
Abstract
Cyclohexadienyl and 6-exo-methyl- or -phenyl-cyclohexadienyl complexes bearing halogeno-, alkoxy-, or dialkyl-amino-substituents in the 1- or 2-positions are obtained by reaction of lithium tetrahydridoaluminate or methyl-or phenyl-lithium with the appropriately substituted (η-arene)tricarbonylmanganese salt. Directive effects in these nucleophilic additions are compared with those observed for arene complexes of iron and chromium.Keywords
This publication has 0 references indexed in Scilit: