Structure of the amine group in m-fluoroaniline by microwave spectroscopy
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 69, 119-125
- https://doi.org/10.1039/f29736900119
Abstract
Microwave spectra of the normal and amine deuterated isotopic species of m-fluoroaniline have been observed. The structure of the amine group determined using the normal isotopic species as the parent molecule is rN–H= 1.00 Å(assumed), ∠ HNH = 115.0°, ϕ= 36.2°(ϕ is the angle between the bisector of the HNH angle and the extension of the CN bond) and is similar to that in aniline. The structure of the amine group determined using m-fluoroaniline-ND2 as the parent molecule is rN–H= 1.00 Å(assumed), ∠ HNH = 117.5°, ϕ= 42.0°.Keywords
This publication has 0 references indexed in Scilit: