Imino Diels–Alder reaction of 2-t-butyldimethylsilyloxycyclohexadiene: isolation of an azabicyclo[2.2.2]octene silyl enol ether adduct
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1601-1602
- https://doi.org/10.1039/c39880001601
Abstract
The imino Diels–Alder reaction of (1) with 2-t-butyldimethylsilyloxycyclohexadiene (2) gave after acidic work-up mainly the bicyclic enol ethers (5a)(for which a novel X-ray crystal structure determination is reported) and (5b) together with small amounts of bicyclic ketones (3a,b) and cyclohexenones (4a,b).Keywords
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