Mono- and Bis-(2,2'- bipyridine) and (1,10-phenanthroline) chelates of ruthenium and osmium. V. Mixed 2,2'-bipyridine and 2,2',2'-terpyridine chelates of bivalent and tervalent osmium
- 1 January 1964
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 17 (6) , 622-631
- https://doi.org/10.1071/ch9640622
Abstract
Complexes of the type [OsterpyCl3]0, [Osterpypy3]2+/3+, [OsterpybipyX]+/2+, [Osterpypy2Cl]+/2+, [Osterpybipy(pyR)]+/2+ where X = Cl, Br, I, NCS, NO2, C2H5CN, CH3CN; R = CH3, C2H5, CH(CH3)2; terpy = 2,2',2"-terpyridine, bipy = 2,2'-bipyridine, and py = pyridine, have been isolated as their halides or perchlorates. The complexes do not disproportionate and are inert to dissociation of their ligands.Keywords
This publication has 0 references indexed in Scilit: