Supramolecular synthons mediated by weak hydrogen bonding: forming linear molecular arrays via CC–H···NC and CC–H···O2N recognition

Abstract
In crystalline 4-cyano-4′-ethynylbiphenyl and 4-ethynyl-4′-nitrobiphenyl, molecules are connected with the hitherto unreported Câ–·C–H···Nâ–·C and Câ–·C–H···O2N supramolecular synthons to form linear arrays.

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