Abstract
The Blume-Emery-Griffiths model is used to model the ordering of semiconducting alloy systems with chalcopyrite structure and zinc-blende structure as the parents, such as the alloy systems (ABD2 )1x(CD)2x or [(AB)1x C2x]D2. The ground states are determined to classify the types of ordering and phase diagrams of the system. The new ordered phases are found at composition x=3/4 and x=1/4 besides the x=1/2 stannite phase for a range of energy parameters. The phase diagrams of the compounds are calculated by the cluster-variation method. Several features of the phase diagrams are discussed and compared with experiment.