Phase diagrams of the Blume-Emery-Griffiths model for semiconducting alloy systems ((CD or [(AB]
- 1 August 1995
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 52 (5) , 3214-3219
- https://doi.org/10.1103/physrevb.52.3214
Abstract
The Blume-Emery-Griffiths model is used to model the ordering of semiconducting alloy systems with chalcopyrite structure and zinc-blende structure as the parents, such as the alloy systems ( (CD or [(AB ]. The ground states are determined to classify the types of ordering and phase diagrams of the system. The new ordered phases are found at composition x=3/4 and x=1/4 besides the x=1/2 stannite phase for a range of energy parameters. The phase diagrams of the compounds are calculated by the cluster-variation method. Several features of the phase diagrams are discussed and compared with experiment.
Keywords
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