A total synthesis of (±)-stemarin, a diterpenoid with a unique bicyclic C/D ring System
- 1 April 1980
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 58 (7) , 755-756
- https://doi.org/10.1139/v80-117
Abstract
A total synthesis of (±)-stemarin, a diterpenoid with a unique C/D ring System, is described. The synthesis features photoaddition of allene to an α,β-unsaturated ketone and two skeletal rearrangements. Application of the synthetic strategy described herein to a synthesis of stemodinol and aphidicolin is anticipated.Keywords
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