Direct observation of the transitions2Δ5/2, ν = 0 →2Π3/2, ν = 0 and2Δ5/2, ν = 0 →2Δ3/2ν = 1 of the NiH radical by Faraday LMR, employing a CO overtone laser
- 10 August 1991
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 73 (5) , 1031-1040
- https://doi.org/10.1080/00268979100101741
Abstract
We report the first direct gas phase observations of the electronic transitions, 2Δ5/2, ν = 0 → 2Π3/2, ν = 0 and 2Δ5/2, ν = 0 → 2Δ3/2, ν = 1, in the NiH radical. From the observed transitions we obtained transition frequencies and electronic g factors. The observation of these electronic transitions by LMR has been possible only by employing the recently developed CO overtone laser. This work forms the first spectroscopic application of this new laser.Keywords
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