Cobalt mediated radical addition–elimination carbon–carbon bond forming reactions in synthesis
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 871-872
- https://doi.org/10.1039/c39870000871
Abstract
Alkyl radicals generated by photolytic homolysis of cobalt ‘salophen’ reagents add to activated carbon–carbon double bonds producing preparatively useful yields of new alkene products; the reactions proceed via radical (Michael) addition, followed by elimination of H–Co.Keywords
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