Synthesis of manoalide using a 1,2-metallate rearrangement
- 1 January 1997
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1139-1140
- https://doi.org/10.1039/a701936j
Abstract
Manoalide, a marine antiinflammatory sesterterpenoid, has been synthesised using a 1,2-metallate rearrangement of a higher order cuprate and a Pd 0 -catalysed carbonylation of an iodo alkene to generate the central dihydropyranone ring.Keywords
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