Arene molybdenum chemistry: arene(π-allyl)molybdenum derivatives containing carboxylate, aminocarboxylate, and related ligands
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 13,p. 1403-1408
- https://doi.org/10.1039/dt9730001403
Abstract
The carboxylato-compounds benzene Mo(π-C3H5)L, where L = O2CH, O2CMe, O2CPh, O2CCH2[Fe(CO)2[π-(π-C5H5)], and related derivatives are described. The complexes where L = NH2CH2CO2 or NH2[CH2]2S have been prepared. The latter reacts with methyl iodide forming the cation {C6H6Mo(π-C3H5)(MeS[CH2]2NH2)}+. β-Diketone derivatives where L = MeCOCHCOMe or MeCOCHCO(OEt) have also been isolated.Keywords
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