Catalysis of aerobic C–C bond cleavage of 1,2-bis(4-methoxyphenyl)ethane-1,2-diol by meso-tetraphenylporphyrinatoiron(III). A model system for cytochrome P-450scc-dependent glycol cleavage
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 381-383
- https://doi.org/10.1039/c39850000381
Abstract
Catalytic cleavage of 1,2-bis(4-methoxyphenyl)ethane-1,2-diol (1a) by chloro(meso-tetraphenylporphyrinato)iron(III) in the presence of N-benzyl-3-carbamoyl-1,4-dihydropyridine under molecular oxygen at room temperature yielded exclusively 4-methoxybenzaldehyde, reproducing most features of the C–C bond cleavage of a venial diol catalysed by cytochrome P-450scc.Keywords
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