Femtosecond transient stimulated emission pumping studies of ozone visible photodissociation
- 1 August 1992
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 97 (3) , 2149-2152
- https://doi.org/10.1063/1.463102
Abstract
We report a new variant of the femtosecond transition-state spectroscopy technique−transient stimulated emission pumping (TSEP). The initial application of TSEP to studies of ozone visible photodissociation indicates that the molecule is trapped in the Franck–Condon region for ∼90 fs. The wave packet then spreads along the reaction coordinate.Keywords
This publication has 17 references indexed in Scilit:
- Detection of ultrafast molecular-excited-state dynamics with time- and frequency-resolved pump-probe spectroscopyPhysical Review A, 1992
- The lowest excited 1A2 and 1B1 states of ozone: Two conical intersections and their impact on photodissociationThe Journal of Chemical Physics, 1991
- Femtosecond transition-state dynamicsFaraday Discussions of the Chemical Society, 1991
- Coherence, transients, and interference in photodissociation with ultrashort pulsesJournal of the Optical Society of America B, 1990
- Ultrafast Reaction DynamicsPhysics Today, 1990
- Ultrafast time-resolved fluorescence spectroscopyPhysical Review A, 1990
- High-power femtosecond dye-laser systemJournal of the Optical Society of America B, 1988
- Ozone visible photodissociation dynamicsThe Journal of Chemical Physics, 1987
- Generation of optical pulses as short as 27 femtoseconds directly from a laser balancing self-phase modulation, group-velocity dispersion, saturable absorption, and saturable gainOptics Letters, 1985
- Chemical dynamics studied by emission spectroscopy of dissociating moleculesThe Journal of Physical Chemistry, 1984