Zur Struktur von Tris(1,3-dimethyl-2-indolyl)-methan: Ein chiraler C3-Propeller aus der Trishetarylmethan-Reihe / The Structure of Tris(1,3-dim ethyl-2-indolyl)m ethane: a Chiral C3-Propeller in the Trishetarylmethane Series
Open Access
- 1 June 1986
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 41 (6) , 762-767
- https://doi.org/10.1515/znb-1986-0614
Abstract
The structure of tris(1,3-dim ethyl-2-indolyl)methane (1) as a model compound for C3-skeleton symmetric trishetaryl-methanes is elucidated by X-ray diffraction and temperature dependant 1H NMR spectroscopy. The results demonstrate, that 1 adopts a chiral C3-propeller conformation (P/M-helix) as well in crystal as in solution.Keywords
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