The trifluorosulphur(VI) oxide cation, SOF3 +

Abstract
It is shown that the adducts SOF4·AsF5 and SOF4·SbF5 have the ionic structure SOF3 +MF6 in the solid state and in solution in hydrogen fluoride: the vibrational spectrum of the SOF3 + ion is assigned and the bonding in the ion is discussed.

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