Flexiblemeso-Bis(sulfinyl) Ligands as Building Blocks for Copper(II) Coordination Polymers: Cavity Control by Varying the Chain Length of Ligands
- 3 September 2001
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 40 (17) , 3201-3203
- https://doi.org/10.1002/1521-3773(20010903)40:17<3201::aid-anie3201>3.0.co;2-z
Abstract
Fillings and cavities: Three novel pseudo‐octahedral metal–organic frameworks, 1–3, consisting of macrometallacyclic noninterpenetrating meso networks and exhibiting weak antiferromagnetic interactions, have been constructed from CuII centers and structurally flexible R,S‐bis(sulfinyl) ligands. Varying the chain length of ligands is found to control the cavity sizes of the networks.This publication has 14 references indexed in Scilit:
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