On the partial molar heat capacity of non-polar gases in aqueous solutions
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 66, 2749-2760
- https://doi.org/10.1039/tf9706602749
Abstract
The anomalous partial molar heat capacity of a non-polar solute in water is discussed in terms of a two-structure model. Interpretation of the various contributions to this quantity is involved even with the simplest model for water. A simple model is designed in which the main features relevant to the problem are included. An exact solution of this model enables a detailed study of the behaviour of the heat capacity in such systems.Keywords
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