Novel redox-active ruthenium cluster crown compounds capable of host–guest chemistry
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 2289-2292
- https://doi.org/10.1039/a803084g
Abstract
The new redox-active cluster compounds [Ru6C(CO)14(η6-C6H4C8H16O5)] and [Ru6C(CO)14(η6-C6H4C10H20O6)] have been synthesised by direct reaction of the aryl crown ether with the hexaruthenium carbido cluster [Ru6C(CO)17] and display host–guest type behaviour with cations Na+ and NH4 + both spectroscopically and electrochemically.Keywords
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