Electron spin resonance studies. Part IL. Radicals derived from oxirans in aqueous solution
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 9,p. 1044-1047
- https://doi.org/10.1039/p29760001044
Abstract
E.s.r. spectroscopy, in conjunction with a flow-system technique, has been used to study the reactions of the hydroxyl radical with some substituted oxirans, and the further transformations (notably ring-opening) of the resulting oxiranyl-substituted radicals. For example, there is evidence that propylene oxide yields, sequentially, the oxiranylmethyl, allyloxyl, and 1-hydroxyallyl radicals.Keywords
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