Impedance Measurements during Anodization of Aluminum

Abstract
The impedance of a growing anodic oxide layer is inductive in a certain frequency range. This effect is related to the occurrence of transients after changes in current density or applied electric field. Measurements on aluminum samples in the frequency range 5 mHz‐10 kHz and the current density range and in various electrolytes are presented and compared with a theory in which the relaxation effect is ascribed to a buildup of surface charge at the metal‐oxide interface.

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