Single crystal electron paramagnetic resonance study of tris (octamethylpyrophosphoramide) copper (II) perchlorate
- 15 December 1973
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 59 (12) , 6312-6320
- https://doi.org/10.1063/1.1680010
Abstract
Single crystal EPR spectra of tris(octamethylpyrophosphoramide) copper (II) perchlorate have been obtained at 90 °K. The results are correlated with x‐ray structural data and evidence is presented in support of a model in which three g tensors are related by the trigonal axis of the unit cell. The model is consistent with the dynamic‐static Jahn‐Teller theory proposed by Abragam and Pryce which assumes the presence of three mutually perpendicular tetragonal distortions of equal energy.Keywords
This publication has 7 references indexed in Scilit:
- Electron paramagnetic resonance studies of some copper(II) complexes with organophosphorus chelatesJournal of the American Chemical Society, 1971
- Structure studies of pyrophosphate chelate rings. I. Crystal structures of tris-octamethylpyrophosphoramide complexes of cobalt(II), magnesium(II), and copper(II)perchloratesInorganic Chemistry, 1970
- The Donor Properties of Pyrophosphate Derivatives. III. A Colorless Copper(II) ComplexJournal of the American Chemical Society, 1966
- The Cupric Ion in a Trigonal Crystalline Electric FieldProceedings of the Physical Society. Section A, 1952
- The theory of the nuclear hyperfine structure of paramagnetic resonance spectra in the copper Tutton saltsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1951
- Theoretical Interpretation of Copper Fluosilicate SpectrumProceedings of the Physical Society. Section A, 1950
- Paramagnetic Resonance in Copper FluosilicateProceedings of the Physical Society. Section A, 1950