α-Trialkylsilylketones from α-bromoketones: utilization of a 1,3-O to C silyl migration
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1746-1747
- https://doi.org/10.1039/c39850001746
Abstract
A new route from α-bromoketones to α-trailkylsilylketones has been developed which demonstrates the viability of halogen-metal exchange vis-a-vis nucleophilic attack at silicon, even with the unhindered trimethylsilyl group.Keywords
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