Circular dichroism of gadolinium(III) tris(oxydiacetate) single crystal
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 78 (3) , 429-433
- https://doi.org/10.1039/f29827800429
Abstract
The electronic absorption and circular dichroism spectra of optically active single crystals of GdIII tris(oxydiacetate) are reported. The relative values of the ratio of rotational strength (RK) to square root of dipole strength (DK) are compared with relative values of the gross magnetic dipole moments of the ƒ→ƒ transitions. The validity of some “soft” selection rules for optical activity, e.g.ΔJ, ΔL 1, are considered.Keywords
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