Total Synthesis of (±)-Virantmycin and Determination of Its Stereochemistry
- 1 January 1991
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1991 (03) , 202-203
- https://doi.org/10.1055/s-1991-20680
Abstract
The stereospecific total synthesis of (±)-virantmycin (1) and its diastereomer (±)-2 were efficiently achieved, featuring an intramolecular nitrene-addition reaction as the key step, without ambiguity in the relative stereochemistry at the two chiral centers (C-2 and C-3).Keywords
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