Tin(II) thiocyanate and complex thiocyanates
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 354-358
- https://doi.org/10.1039/j19690000354
Abstract
The preparation and properties of pure tin(II) thiocyanate and of several complex thiocyanates are described. Their infrared spectra are discussed and evidence is adduced for mainly N-bonding of the thiocyanate, with extensive bridging in Sn(NCS)2. Tin(II) thiocyanate is found to form ether adducts of poor stability and to be an effective catalyst for polyurethane foam formation. X-Ray powder data are given for Sn(NCS)2, KSn(SO)4NCS, CsSn(NCS)3, Me4NSn(NCS)3, and Et4NSn(NCS)3.Keywords
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