Homogeneous hydrogenation of the –NN–, –CHN–, and –NO2groupings
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 11,p. 626a
- https://doi.org/10.1039/c2970000626a
Abstract
Using the previously described (py)3RhCl3–NaBH4 catalyst in dimethylformamide with hydrogen, azobenzene is reduced to hydrazobenzene and slowly to aniline, benzalaniline gives benzylaniline, and nitrobenzene is reduced to aniline; pyridine and quinoline are hydrogenated to give piperidine and 1,2,3,4-tetrahydroquinoline respectively.Keywords
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