Intramolecular hydrogen bonds in monosaccharides in dimethyl sulfoxide solution

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Abstract
By the use of the SIMPLE NMR method, strong intramolecular hydrogen bonds were found in the Me2SO solutions of sugars having two syn-axial hydroxy groups, like the talopyranoses. Weaker hydrogen bonds were detected between hydroxy groups in a 1,3-arrangement when one was outside the ring but only weak, although numerous, hydrogen bonds were detected in solutions of other sugars and inositols.

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