Comment on the pair correlation function in an inhomogeneous liquid: A test of the Fischer approximation
- 15 May 1987
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 86 (10) , 5731-5733
- https://doi.org/10.1063/1.452499
Abstract
Using the results of Monte Carlo simulations of cesium, we demonstrate that the simple point local density approximation is inaccurate in predicting the behavior of the transverse pair correlation function in the liquid–vapor interface of a simple metal. Our calculations demonstrate that a local density approximation, such as the one proposed by Fischer and Methfessel, which uses the point density averaged over a region the size of the ion, more accurately describes the behavior of the transverse pair correlation function.Keywords
This publication has 12 references indexed in Scilit:
- A self-consistent Monte Carlo simulation of the electron and ion distributions in the liquid–vapor interface of a simple metalThe Journal of Chemical Physics, 1987
- Perturbation theory of liquid-metal surfaces: The importance of the self-energyPhysical Review A, 1984
- Experimental study of the density profile in the liquid–vapor interface of mercuryThe Journal of Chemical Physics, 1984
- Experimental investigation of the density profile in the liquid-vapor interface of mercury and galliumJournal of Non-Crystalline Solids, 1984
- An x-ray reflectance study of the liquid–vapor interface of CsThe Journal of Chemical Physics, 1983
- A study of the liquid–vapor interface of mercury: Computer simulation resultsThe Journal of Chemical Physics, 1983
- Born-Green-Yvon approach to the local densities of a fluid at interfacesPhysical Review A, 1980
- Monotonic and oscillatory density profiles at the free liquid surface for simple atomic fluidsMolecular Physics, 1980
- Monte Carlo study of a hard-sphere fluid near a hard wallThe Journal of Chemical Physics, 1978
- Hydrostatic equilibrium in fluid interfacesThe Journal of Chemical Physics, 1976