Cyclometallation reactions of 6-phenyl-2,2′-bipyridine; a potential C,N,N-donor analogue of 2,2′: 6′,2″-terpyridine. Crystal and molecular structure of dichlorobis(6-phenyl-2,2′-bipyridine)ruthenium(II)
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 443-449
- https://doi.org/10.1039/dt9900000443
Abstract
Metallated and non-metallated complexes of the ligand 6-phenyl-2,2′-bipyridine (HL) with ruthenium(II), rhodium(II), platinum(II), palladium(II), and gold(III) have been prepared. The crystal and molecular structure of the complex [Ru(HL)2Cl2][triclinic, a= 8.671(1), b= 10.360(2), c= 16.139(3)Å, α= 89.18(2), β= 81.26(1), γ= 67.11 (1)°, direct methods, least-squares refinement and Fourier difference synthesis, R= 0.0310, R′= 0.0359] indicates that it contains two N-bonded ligands and a cis arrangement of the chlorides.Keywords
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