Flash photolysis of Cr(CO)6 in H2-saturated cyclohexane solution: i.r. spectroscopic evidence for a Cr(CO)5(H2) complex at room temperature
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 30-32
- https://doi.org/10.1039/c39850000030
Abstract
Flash photolysis of Cr(CO)6 in H2-saturated cyclohexane Solution leads to the formation of Cr(CO)5(H2) as a relatively stable transient (k= 2.5 s–1 at room temperature); Cr(CO)5(H2) is identified by kinetic i.r. spectroscopy, including D2 isotpe effects.Keywords
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