Tetrameric cyano-rhenium complexes with sulphur and selenium bridges: preparation and X-ray crystal structures of (Ph4P)4[Re4S4(CN)12]·3H2O and (Ph4P)4[Re4S4(CN)12]·3H2O
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 221-222
- https://doi.org/10.1039/c39770000221
Abstract
The anions [Re4(µ3-S)4(CN)12]4– and [Re4(µ3-Se)4(CN)12]4– each contain a tetrahedron of Re atoms held together by short Re–Re bonds, with one triply bridging S or Se atom per face of the tetrahedron.Keywords
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