Formation of Lead Zirconate‐Lead Titanate Solid Solutions
- 2 June 1965
- journal article
- Published by Wiley in Journal of the American Ceramic Society
- Vol. 48 (6) , 289-291
- https://doi.org/10.1111/j.1151-2916.1965.tb14743.x
Abstract
Formation of the Pb(Zr,Ti)O3 solid solution in the system PbO‐TiO2‐ZrO2 was studied by chemical analysis and X‐ray powder diffrac‐tometry. Only PbTiO3 and Pb(Zr,Ti)O3 were found as reaction products. The following three elementary reactions seemed to be reasonable for the formation of the Pb(Zr,Ti)O3 phase: PbO + TiO2→ PbTiO3, PbTiO3+ PbO + ZrO2→Pb(Zr1‐λTiλ)O3, and Pb(Zrl‐λTiλ)O3+ PbTiO3→ Pb(Zr1‐λ′Tiλ′)O3 (λ<λ′).Keywords
This publication has 13 references indexed in Scilit:
- Introduction of Particle‐Size Distribution into Kinetics of Solid‐State ReactionJournal of the American Ceramic Society, 1964
- FUNDAMENTAL STUDIES ON METHODS OF PRACTICE FOR PREPACKED CONCRETETransactions of the Japan Society of Civil Engineers, 1963
- A Ternary System PbO-TiO2-ZrO2Japanese Journal of Applied Physics, 1962
- On the High Permittivity Ceramics Containing PbO, the Evaporation of PbO at High TemperaturesJournal of the Ceramic Association, Japan, 1958
- Properties of piezoelectric ceramics in the solid-solution series lead titanate-lead zirconate-lead oxide: Tin oxide and lead titanate-lead hafnateJournal of Research of the National Bureau of Standards, 1955
- Piezoelectric Properties of Lead Zirconate-Lead Titanate Solid-Solution CeramicsJournal of Applied Physics, 1954
- Phase Transitions in Solid Solutions of PbZrO3 and PbTiO3 (I) Small Concentrations of PbTiO3Journal of the Physics Society Japan, 1952
- Phase Transitions in Solid Solutions of PbZrO3and PbTiO3(II) X-ray StudyJournal of the Physics Society Japan, 1952
- Lead Titanate: Crystal Structure, Temperature of Formation, and Specific Gravity DataThe Journal of Physical Chemistry, 1937
- Chemische Reaktionen in pulverförmigen Gemengen zweier KristallartenZeitschrift für anorganische und allgemeine Chemie, 1925